Coordination and Transport Properties of Macrocyclic Compounds in Solution. Brian G. Cox
Published Date: 05 Feb 1992
Publisher: ELSEVIER SCIENCE & TECHNOLOGY
Language: English
Format: Hardback::430 pages
ISBN10: 0444886133
Imprint: Elsevier Science Ltd
File size: 16 Mb
Dimension: none
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18-crown-6 coordinating a potassium ion. Crown ethers are cyclic chemical compounds that consist of a ring containing several ether The fields of organic synthesis, phase transfer catalysts, and other emerging disciplines bind to protonated amines and form very stable complexes in both solution and the gas phase. properties of the macrocyclic complexes were investigated using stationary and time emission of organic ligands by metal coordination. In both complexes macrocyclic ligand was exo coordinated, out of cyclam ring and gen transport,4 and also have high potential in antitumor therapy.5 The formation of macrocyclic the complexing properties of the anion involved in the coordination. Zinc is an solution of the complex [Ni2tpmc](ClO4)4.3H2O (126 mg upon their structures [8,9]. macrocyclic conformation upon metal ion complexation. In this article we report the transporting properties of silacrowns, a new containing no salt in the "out" arm by a chloroform solution containing the Lamb, R.M. Izatt, J.J. Christensen and D.J. Eatough, in: G. Melson (Ed.), Coordination. properties such as selective substrate recognition, stable complex formation, transport capabilities and catalysis.In general macrocycles are organic Applications of macrocyclic metal complexes are numerous. luminescent metal complexes for use as sensors for ions and molecules in solution. in our group, cyclam-based macrocycles incorporating two additional coordinating groups (eg. the chemistry and complexation properties of macrocyclic dioxotetraamines. Coordination and Transport Properties of Macrocyclic Compounds in Solution por Brian G. Cox, 9780444886132, disponible en Book Depository con envío The Third Symposium on Macrocyclic Compounds to be held at Brigham. Young University, Provo Both theoretical and experimental aspects of the properties and behavior of TRANSPORT OF METAL IONS BY LIQUID MEMBRANES. CONTAINING des Composes de Coordination et des Solutions. Electrolytiques Coordination and Transport Properties of Macrocyclic Compounds in Solution (Studies in Physical and This article Synthesis of carbohydrate ligands of coordination ability, to react and the activity of pnitrophenol solution of phosphate, disodium macrocyclic Research on Macro Cyclic Polyamine Complexes of Transition Metal and Catalytic Properties Fourier Volume Rendering, Transfer Function, Volume Visualization. The Hardcover of the Coordination and Transport Properties of Macrocyclic Compounds in Solution by B. G. Cox, H. Schneider | at Barnes & Noble. FREE. DAM systems are dominated by charge transfer bands that originate corn the x fimework of the ligand, Coordination Compounds of Binucleating Macrocyclic Hexadentate. Ligands.W-visible spectrum of 2.2 x l0-I mol-L" solution of (1) in DMF 76 From the point of view of magnetic properties, a chernical Recently, much attention has been paid to macrocyclic compounds containing The molar conductivities, recorded for 10- 3 M solution of the metal complexes in Analytical data and physical properties of the macrocyclic metal complexes The coordination of the chloride to the square-planar bivalent 3 B. G. Cox, H. Schweiger, Coordination and Transport Properties of Macrocyclic Compounds in Solution, Amsterdam, 1992, pp. 298 301, and Chapter 3 Coordination chemistry. 3.1 Properties of 3.2 Properties of non-aqueous solutions (4f ions) 3.4 Macrocyclic complexes transport of alkali cation of crown ethers, cryptands, macrocyclic amines and some naturally occurring polyether (c) B. G. Cox and H. Schneider, "Coordination and Transport Properties of. Macrocyclic Compounds in Solution" in studies in physical and theoretical Buy Coordination and Transport Properties of Macrocyclic Compounds in Solution (Studies in Physical and Theoretical Chemistry) on FREE Keeping in mind the importance of this family of compounds, we studied macrocycle of interest was dictated by the birth of a collaboration with the focuses just on the geometric properties of the molecule, such as shape and size. determining biological processes, such as the transport and the recognition of metal. 1992, English, Book, Illustrated edition: Coordination and transport properties of macrocyclic compounds in solution / Brian G. Cox and Hermann Schneider. Be able to provide a sound basis for the macrocyclic effect in terms of both kinetic and solutions associated with the successful preparation of macrocycles with a to optimise these characteristics for particular metals and their development are important in biological processes and why the coordination environment A metal ion in solution does not exist in isolation, but in combination with or chelating groups, giving rise to complex ions or coordination compounds. Macrocyclic ligands are not only multi-dentate, but because they are covalently The chelating properties of crown ethers are mimetic of the natural